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Journal article
Negative ion electrospray mass spectrometry of neoflavonoids
The electrospray ionisation mass spectra of the neoflavanoids brazilin and hematoxylin are reported in both their reduced (1 and 2, respectively) and their oxidised forms (3 and 4, respectively). In the reduced forms, breakdown pathways under collision induced decomposition (CID) conditions produce fragments characteristic of rings A and C; in...Hulme, Alison N ; McNab, Hamish ; Peggie, David A ; Quye, Anita
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Journal article
2',4',6'-Trihydroxy-1-methoxyacetophenone monohydrate at 150 K
The geometry of the title compound, 2-methoxy-1-(2,4,6-trihydroxyphenyl)ethanone, C9H10O5·H2O, is determined by the presence of an intramolecular hydrogen bond; the geometry of the benzene ring is distorted by a flanking carbonyl group.Ferreira, Ester S B ; Hulme, Alison N ; McNab, Hamish ; Quye, Anita ; Parsons, S
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Journal article
The natural constituents of historical textile dyes
The sources and structures of dyes used to colour Western historical textiles are described in this tutorial review. Most blue and purple colours were derived from indigo—obtained either from woad or from the indigo plant—though some other sources (e.g. shellfish and lichens) were used. Reds were often anthraquinone derivatives obtained...Ferreira, Ester S B ; Hulme, Alison N ; McNab, Hamish ; Quye, Anita
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2009
Journal article
Negative ion ESI–MS analysis of natural yellow dye flavonoids : an isotopic labelling study
Flavonoids are amongst the most commonly used natural yellow colourants in paintings, as lakes, and in historical textiles as mordant dyes. In this paper, evidence from isotopically labelled substrates is used to propose negative ion electrospray collision induced decomposition mechanisms of flavones, flavonols and an isoflavone. These mechanisms include a...McNab, Hamish ; Ferreira, Ester S B ; Hulme, Alison N ; Quye, Anita
Flavonoids , Historical textiles, Lake pigments, and Electrospray