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Journal article
Synthesis and reactions of 4-aryloxyflavans
4α-Aryloxyflavans unsubstituted in ring A have been synthesised by the reaction of phenols with flavan-4β-ols in the presence of boron trifluoride in ether. If reaction times are prolonged beyond disappearance of the starting 4β-ols, thermodynamic control leads to 4-arylflavans and the yields of 4-aryloxyflavans are negligible. 4-Arylflavans are the sole...Bateman, G ; Brown, B R ; Campbell, J B ; Cotton, C A ; Johnson, P …